Date of Award

1-1-2011

Language

English

Document Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

College/School/Department

Department of Chemistry

Content Description

1 online resource (xii, 165 pages) : illustrations (some color)

Dissertation/Thesis Chair

John T Welch

Committee Members

Lawrence C Snyder, Marina Petrukhina, Charles P Scholes, Fatemeh Shahedipour-Sandvik

Keywords

computational chemistry, eigenstates, graphene, hexagonal BN, perturbation theory, zone folding, Boron nitride, Carbon composites, Density functionals, Lattice theory

Subject Categories

Chemistry | Condensed Matter Physics | Physical Chemistry

Abstract

The electronic structures of systems consisting of hexagonal boron nitride layers and graphite sheets have been investigated in detail using density functional theory methods with two exchange correlation functions (local density approximation and generalized gradient approximation). The experimental data of graphene, graphite, monolayer hexagonal BN, and hexagonal BN were reproduced well with computational models. The commensurate models used in the investigation were generated by taking the averages of the lattice constants for graphite and h-BN.

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