Date of Award

8-1-2022

Language

English

Document Type

Dissertation

Degree Name

Doctor of Philosophy (PhD)

College/School/Department

Department of Chemistry

Content Description

1 online resource (xiii, 172 pages) : illustrations (some color)

Dissertation/Thesis Chair

Alan A Chen

Committee Members

Alexander Shektman, Mehmit Yigit, Gabrielle Fuchs, Michael Yeung

Keywords

Ion mobility mass spectrometry, Nucleic acids

Subject Categories

Analytical Chemistry | Biochemistry | Computational Chemistry

Abstract

Ion mobility spectrometry - mass spectrometry (IMS-MS) has potential for the investigation of structure and dynamics in large biopolymers, which will come to full fruition only with a firmer understanding of how to interpret the experimental data. Numerous studies have employed elements of nucleic acid (NA) secondary structure, such as duplexes and hairpins, to explore the relationships between structure, experimental conditions, and actual observations. When combined with molecular dynamics simulations (MDS), IMS-MS can be effectively employed to perform structural elucidation of biomolecules that are not readily amenable to established techniques employed for structural analysis.

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