Date of Award
1-1-2017
Language
English
Document Type
Dissertation
Degree Name
Doctor of Philosophy (PhD)
College/School/Department
Department of Chemistry
Content Description
1 online resource (iii, viii, 356 pages) : illustrations (some color)
Dissertation/Thesis Chair
John T Welch
Committee Members
Jan Halamek, Paul J Toscano, Ting Wang, Maksim Royzen
Keywords
Hypervalent sulfur fluorides, organic fluorine, Tetrafluorsulfanyl, Fluorocarbons, Alkynes, Alkenes, Aromatic fluorine compounds, Polysulfides
Subject Categories
Organic Chemistry
Abstract
Synthetic access to systematically substituted tetrafluoro-λ6-sulfanes was challenging and the research in this area had been largely abandoned. The original reports of disubstituted-tetrafluoro-λ6-sulfanes were limited to substitution by diphenyl and dialkyl groups. The dialkyl-tetrafluoro-λ6-sulfanes were reactive while the diphenyl substituted compounds showed decreased reactivity. In this dissertation, the systematic substitution on tetrafluoro-λ6-sulfanes has enabled the studies of the substitution effects on reactivity.
Recommended Citation
Zhong, Linbin, "The preparation and characterization of tetrafluoro-lambda~6~-sulfanes" (2017). Legacy Theses & Dissertations (2009 - 2024). 1987.
https://scholarsarchive.library.albany.edu/legacy-etd/1987