Date of Award
1-1-2015
Language
English
Document Type
Dissertation
Degree Name
Doctor of Philosophy (PhD)
College/School/Department
Department of Chemistry
Content Description
1 online resource (xxii, 352 pages) : color illustrations.
Dissertation/Thesis Chair
John T. Welch
Committee Members
Rabi A. Musah, Evgeny V. Dikarev, Daniele Fabris, George L. Barnes
Keywords
Aldehydes, Computation, Pentafluorosulfanyl, Preparation, SF5, Staudinger, Organosulfur compounds, Fluorine compounds, Hypervalence (Theoretical chemistry), Aliphatic compounds
Subject Categories
Chemistry | Organic Chemistry
Abstract
Since the discovery of the pentafluorosulfanyl (SF5) group around the 1960s, progress in exploring the chemistry of aliphatic SF5-containing compounds stagnated because of a lack of efficient synthetic methods. More recent developments in the preparations of SF5-containing compounds afforded easier access to these compounds, and sparked great interest in exploring their chemistry. Chapter 1 discusses the development of efficient methods used to prepare SF5-containing aliphatic compounds.
Recommended Citation
Savoie, Paul R., "Preparation, chemistry, and characterization of hypervalent organosulfur fluorides" (2015). Legacy Theses & Dissertations (2009 - 2024). 1497.
https://scholarsarchive.library.albany.edu/legacy-etd/1497