Date of Award
1-1-2009
Language
English
Document Type
Dissertation
Degree Name
Doctor of Philosophy (PhD)
College/School/Department
Department of Physics
Content Description
1 online resource (xiv, 189 pages) : PDF file, illustrations (some color)
Dissertation/Thesis Chair
Keith A Earle
Committee Members
Keith A Earle, Kevin H Knuth, John Kimball, Carolyn MacDonald, Chittibabu Guda
Keywords
Electron paramagnetic resonance, Nitroxides, Vanadium compounds
Abstract
This present work consists of multifrequency Electron Paramagnetic Resonance (EPR) studies of the model compounds by performing EPR experiments on Vanadyl acetylacetonate [VO(acac)2] and Vanadyl meso-tetraphenylporphin [VO(TPP)] at different frequencies (3GHz, 9.9GHz, 23.8GHz, 34GHz and 95GHz) in motional narrowing regime and at 9.9 GHz in rigid limit regime. Additional experiments were performed on PD-Tempone (Perdeuterated 2, 2, 6, 6-Tetramethyl-4-piperidone N-Oxide) spin labels in Cyclodextrins and glycerol/water mixtures at 9.3GHz from the rigid limit to the motional narrowing regime.
Recommended Citation
Sahu, Indra Dev, "Multifrequency EPR studies on vanadyl and nitroxide complexes via bayesian inference, relativistic density functional theory, and lineshape analysis" (2009). Legacy Theses & Dissertations (2009 - 2024). 107.
https://scholarsarchive.library.albany.edu/legacy-etd/107